This dataset includes wavelength dispersive X-ray fluorescence (WD-XRF) major-oxide and trace-element whole-rock analyses, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) trace-element whole-rock analyses, and glass analyses by electron microprobe of scoria and lava samples from the Kamakaiʻa Hills of the Southwest Rift Zone of Kīlauea volcano, Island of Hawaiʻi. Whole-rock chemical analyses were performed at the Hamilton Analytical Laboratory at Hamilton College in Clinton, New York, USA, whereas glass chemical analyses were performed at the U.S. Geological Survey in Menlo Park, California, USA.